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Researchers at Rice University have discovered a method of industrial-scale processing of pure carbon nanotube fibers. The breakthrough is the result of a nine-year program and the method builds on the processes that have been used by chemical firms for decades to produce plastics.
Researcher Matteo Pasquali from Rice said, "Plastics is a $300 billion U.S. industry because of the massive throughput that's possible with fluid processing. The reason grocery stores use plastic bags instead of paper and the reason polyester shirts are cheaper than cotton is that polymers can be melted or dissolved and processed as fluids by the train-car load. Processing nanotubes as fluids opens up all of the fluid-processing technology that has been developed for polymers."
The researchers report that the new process builds on a discovery made in 2003 at Rice that found a way to dissolve large amounts of pure nanotubes in strong acetic solvents like sulfuric acids. The team of researchers found with further investigation that the nanotubes dissolved in the acidic solutions aligned themselves like spaghetti in a package to form liquid crystals that could then be spun into monofilament fibers about as thick as a human hair.
Researcher Wade Adams said, "That research established an industrially relevant process for nanotubes that was analogous to the methods used to create Kevlar from rodlike polymers, except for the acid not being a true solvent. The current research shows that we have a true solvent for nanotubes -- chlorosulfonic acid -- which is what we set out to find when we started this project nine years ago."
DailyTech - Rice University Researchers Make Breakthrough in Carbon Nanotube Processing
Researcher Matteo Pasquali from Rice said, "Plastics is a $300 billion U.S. industry because of the massive throughput that's possible with fluid processing. The reason grocery stores use plastic bags instead of paper and the reason polyester shirts are cheaper than cotton is that polymers can be melted or dissolved and processed as fluids by the train-car load. Processing nanotubes as fluids opens up all of the fluid-processing technology that has been developed for polymers."
The researchers report that the new process builds on a discovery made in 2003 at Rice that found a way to dissolve large amounts of pure nanotubes in strong acetic solvents like sulfuric acids. The team of researchers found with further investigation that the nanotubes dissolved in the acidic solutions aligned themselves like spaghetti in a package to form liquid crystals that could then be spun into monofilament fibers about as thick as a human hair.
Researcher Wade Adams said, "That research established an industrially relevant process for nanotubes that was analogous to the methods used to create Kevlar from rodlike polymers, except for the acid not being a true solvent. The current research shows that we have a true solvent for nanotubes -- chlorosulfonic acid -- which is what we set out to find when we started this project nine years ago."
DailyTech - Rice University Researchers Make Breakthrough in Carbon Nanotube Processing