What happens when we take due consideration of emissivities for surface and atmosphere?
At 15 microns the atmosphere is black, all surface 15 micron radiation is absorbed within the first few metres.
At 10 microns the atmosphere is clear, the surface radiation is almost totally transmitted out to space as if the atmosphere was not even there.
Cloud are more like liquid water than a gas so they have more bonds to absorb a variety of photons than does water vapour.
Show me an actual measurement made with an instrument at ambient temperature that establishes a coherent relationship between the absorption of IR by a gas and warming in the atmosphere...leave your models at home...show me some actual evidence...something that illustrates more than the already obvious fact that you are easily fooled by instrumentation.
Do you actually believe the instruments are giving the wrong readings? They appear to be thoroughly repeatable. Are you questioning their precision or their accuracy?