As the altitude of the molecule grows from the ground the chances a photon can be re-emitted towards the ground become less and less.
Can you explain further?
The laws of probability become near zero at just five meters at levels of 1000 ppm.
Near 0% chance that a photon can be emitted downward? Seems unlikely, but please, expound.
Billy Bob, you seem to be confused here as to the difference between TO THE GROUND and TOWARDS THE GROUND. At any point in it's travels, the directional odds of photon emission from a gas molecule are precisely equal in all directions. If we were at, say geosynchronous orbit we might say there's a reduction in the odds because the Earth itself subtends less of our view. But within the atmophere, there is very, very little drop in the geometric probabilities.
Your argument here is blatant nonsense.