mamooth
Diamond Member
Appeal to authority doesn't constitute a rational argument and since you are the one making the claim that I am wrong, of course it falls to you to prove it.
Your extraordinary claims require extraordinary evidence to back them up. You're saying the rest of planet is wrong. If you want to overturn that, you'll have to do a bit better than endless repetitions of "BECAUSE I SAY SO!".
Of course they can, and do. But not spontaneously. Some work must be done to move them from a low energy state to a high energy state.
Molecule absorbs backradiation photon, jumps to higher vibrational state. It's not complicated. You've just got this emotional block. You don't understand because you willfully don't want to understand.
You claimed that the second law only covered convection
Even accounting for your convection/conduction gaffe, I still didn't say that. I said that one particular phrasing of the second law (there are many different ways to say it), the one saying heat flows from hot to cold, refers only to conduction. And that's correct.
Radiative heat flows from hot to hotter quite freely. Deny it all you want, but the universe isn't going to pay attention to your kook rambling.