thats odd. where did your last post go wirebender? do you mind putting that link up again, my phone doesnt have a history on the browser.
its an interesting idea but I am not really sure that it is fair to compare emissivity of CO2 over a large range when we are interested in IR that the earth gives off. CO2 has a couple of fat bands right in the middle of earth's radiation, with the 15 micron band practically to itself.
judging from the big bite taken out of the 15 micron portion of TOA outward radiation it appears that CO2 does a pretty good job of absorbing that band of radiation. actually I would like to read a paper on how much more energy can even be stopped because it looks like most already has been. I suppose that is why we are in the low slope portion of the log scale for doubling CO2 concentration.
Well if You want to read a paper on it here it is, these are ACTUAL MEASUREMENTS,...:
The Climate Catastrophe - A Spectroscopic Artifact
[FONT=Arial, Geneva]A 10 cm glass cylinder (150 cm[SIZE=-2]3[/SIZE], with IR-transparent window) was filled with synthetic CO[SIZE=-2]2[/SIZE]-free and vapour-free air. Then a microlitre syringe was used to add CO[SIZE=-2]2[/SIZE] so that the concentration was 357 ppm (concentration in 1993). Moreover 2.6% water vapour was added. Applying the IR beam source (a so-called Globar , an electrically heated silicon carbide bar at 1000 to 1200 degC and an adjustable interference filter) on one side, the absorption spectrum arriving at the other end was recorded. Then CO[SIZE=-2]2[/SIZE] was added to make 714 ppm. The equipment was an FTIR spectrometer "Bruker IFS 48" coupled to a PC. The program OPUS was used as analyzing software. A zero bias measurement was made to be subtracted later.[/FONT]
and here are the results:
[FONT=Arial, Geneva]Crucial is the relative increment of greenhouse effect . This is equal to the difference between the sum of slope integrals for 714 and 357 ppm, related to the total integral for 357 ppm. Considering the n[SIZE=-2]3[/SIZE] band alone (as IPCC does) we get[/FONT]
[FONT=Arial, Geneva](9.79[SIZE=+1]*[/SIZE]10[SIZE=-2]-4[/SIZE] cm[SIZE=-2]-1[/SIZE] - 1.11[SIZE=+1]*[/SIZE]10[SIZE=-2]-4[/SIZE] cm[SIZE=-2]-1[/SIZE]) / 0.5171 cm[SIZE=-2]-1[/SIZE] = 0.17 %[/FONT]
[FONT=Arial, Geneva] Conclusions[/FONT]
[FONT=Arial, Geneva]It is hardly to be expected that for CO[SIZE=-2]2[/SIZE] doubling an increment of IR absorption at the 15 µm edges by 0.17% can cause any significant global warming or even a climate catastrophe.[/FONT]
[FONT=Arial, Geneva]The radiative forcing for doubling can be calculated by using this figure. If we allocate an absorption of 32 W/m[SIZE=-2]2[/SIZE] [SIZE=-1][14][/SIZE] over 180º steradiant to the total integral (area) of the n[SIZE=-2]3[/SIZE] band as observed from satellite measurements [SIZE=-1](Hanel et al., 1971)[/SIZE] and applied to a standard atmosphere, and take an increment of 0.17%, the absorption is 0.054 W/m[SIZE=-2]2[/SIZE] - and not 4.3 W/m[SIZE=-2]2[/SIZE].[/FONT]
[FONT=Arial, Geneva]This is roughly 80 times less than IPCC's radiative forcing.[/FONT]
[FONT=Arial, Geneva]If we allocate 7.2 degC as greenhouse effect for the present CO[SIZE=-2]2[/SIZE] (as asserted by Kondratjew and Moskalenko in J.T. Houghton's book The Global Climate [SIZE=-1][14][/SIZE]), the doubling effect should be 0.17% which is 0.012 degC only. If we take 1/80 of the 1.2 degC that result from Stefan-Boltzmann's law with a radiative forcing of 4.3 W/m[SIZE=-2]2[/SIZE], we get a similar value of 0.015 degC.[/FONT]