Old Rocks
Diamond Member
CO2 residence time is short and meaningless. The vast majority of evidence says that the CO2 levels are increasing because of the warmth not causing it.
Atmospheric Residence Time of Man-Made CO2
Potential Dependence of Global Warming on the Residence Time (RT) in the Atmosphere of Anthropogenically Sourced Carbon Dioxide
Robert H. Essenhigh
Department of Mechanical Engineering, The Ohio State University, Columbus, Ohio 43210
Energy Fuels, 2009, 23 (5), pp 27732784
DOI: 10.1021/ef800581r
Publication Date (Web): April 1, 2009
Copyright © 2009 American Chemical Society
Abstract:
The driver for this study is the wide-ranging published values of the CO2 atmospheric residence time (RT), τ, with the values differing by more than an order of magnitude, where the significance of the difference relates to decisions on whether (1) to attempt control of combustion-sourced (anthropogenic) CO2 emissions, if τ > 100 years, or (2) not to attempt control, if τ 10 years. This given difference is particularly evident in the IPCC First 1990 Climate Change Report where, in the opening policymakers summary of the report, the RT is stated to be in the range of 50−200 years, and (largely) on the basis of that, it was also concluded in the report and from subsequent related studies that the current rising level of CO2 was due to combustion of fossil fuels, thus carrying the, now widely accepted, rider that CO2 emissions from combustion should therefore be curbed. However, the actual data in the text of the IPCC report separately states a value of 4 years. The differential of these two times is then clearly identified in the relevant supporting documents of the report as being, separately (1) a long-term (100 years) adjustment or response time to accommodate imbalance increases in CO2 emissions from all sources and (2) the actual RT in the atmosphere of 4 years. As a check on that differentiation and its alternative outcome, the definition and determination of RT thus defined the need for and focus of this study. In this study, using the combustion/chemical-engineering perfectly stirred reactor (PSR) mixing structure or 0D box for the model basis, as an alternative to the more commonly used global circulation models (GCMs), to define and determine the RT in the atmosphere and then using data from the IPCC and other sources for model validation and numerical determination, the data (1) support the validity of the PSR model application in this context and, (2) from the analysis, provide (quasi-equilibrium) RTs for CO2 of 5 years carrying C12 and 16 years carrying C14, with both values essentially in agreement with the IPCC short-term (4 year) value and, separately, in agreement with most other data sources, notably, a 1998 listing by Segalstad of 36 other published values, also in the range of 5−15 years. Additionally, the analytical results also then support the IPCC analysis and data on the longer adjustment time (100 years) governing the long-term rising quasi-equilibrium concentration of CO2 in the atmosphere. For principal verification of the adopted PSR model, the data source used was the outcome of the injection of excess 14CO2 into the atmosphere during the A-bomb tests in the 1950s/1960s, which generated an initial increase of approximately 1000% above the normal value and which then declined substantially exponentially with time, with τ = 16 years, in accordance with the (unsteady-state) prediction from and jointly providing validation for the PSR analysis. With the short (5−15 year) RT results shown to be in quasi-equilibrium, this then supports the (independently based) conclusion that the long-term (100 year) rising atmospheric CO2 concentration is not from anthropogenic sources but, in accordance with conclusions from other studies, is most likely the outcome of the rising atmospheric temperature, which is due to other natural factors. This further supports the conclusion that global warming is not anthropogenically driven as an outcome of combustion. The economic and political significance of that conclusion will be self-evident.
CO2 has a short residence time
The claim goes like this:
(A) Predictions for the Global Warming Potential (GWP) by the IPCC express the warming effect CO2 has over several time scales; 20, 100 and 500 years.
(B) But CO2 has only a 5 year life time in the atmosphere.
(C) Therefore CO2 cannot cause the long term warming predicted by the IPCC.
This claim is false. (A) is true. (B) is also true. But B is irrelevant and misleading so it does not follow that C is therefore true.
The claim hinges on what life time means. To understand this, we have to first understand what a box model is: In an environmental context, systems are often described by simplified box models. A simple example (from school days) of the water cycle would have just 3 boxes: clouds, rivers, and the ocean.
A representation of the carbon cycle (ignore the numbers for now) would look like this one from NASA.