I cant believe you have taken any physics courses. atoms and molecules absorb and emit the exact same wavelengths. it is the principle used in spectography.
Then ian, you know exactly jack about spectrography. Tell me ian, how do you suppose the energy that a CO2 atom absorbs causes a vibration within the molecule without expending some small bit of the energy? Do you believe that vibration happens without the loss of any energy at all? And if there is some energy expended in causing the vibration, how could the molecule emit exactly the same frequency as it absorbed.
Again, you are so far off here that I am becoming embarassed for you.
I suggest that you read this and try your best to actually learn something from it.
Jennifer Marohasy » Recycling of Heat in the Atmosphere is Impossible: A Note from Nasif S. Nahle
it really is interesting trying to deduce what your understandings and misunderstandings are.
perhaps we should find out what we agree upon first. quantum mechanics is based on the principle that electrons can only occupy certain energy states in the atom, otherwise the electron would radiate its energy and collapse into the nucleus. next, an incident photon with the correct amount of energy can knock an electron into a higher orbital (quantum state) but that electron wants to shed energy so it emits one or more photons as it jumps back down to groundstate in one or more individual steps. the various paths that electrons can take match up to the emission and absorption spectra. are we OK so far?
with molecules it is more complex. CO2 has three vibrational modes that are activated by incident IR photons. the molecule either vibrates or it doesnt, there is no half vibration, no 'leaking' of energy. I am unaware of one vibrational state transforming to another but it is possible.
molecular collisions also add to the complexity. polar bear had an interesting analogy to bumper cars that deform the electron envelope storing energy, then release it. I will not agree or disagree with that possibility although it seems like an interesting way to produce blackbody radiation.
your link says that the radiation going into CO2 is followed by radiation coming out at longer wavelengths and lower energy. I have no problem with that. it is to be expected, entropy increases. what I do have a problem with is you stating that an atom or molecule can emit radiation that cannot be accepted by the same type of molecule or atom. some wavelengths will be less preferencially absorbed, especially if they are partial early steps down the quantum ladder to groundstate when a higher energy photon is transformed into two or more lower energy photons.
my question to you is this. any normal energy reaction is reversible although the reaction rates are effected by entropy as the arrow of time. so even if the reaction goes 99% one way it is incorrect to say that the other way is impossible. and yet you keep proclaiming all sorts of things are impossible just because they are less likely. the SLoT is a numerical description of systems. even if something is only slightly more favoured it is close to a statistical certainty when multiplied by 100 iterations, or a trillion, or ten to the 24th power.
quite often what you have to say is somewhat correct in reality but your stated reasons for what happened are totally wrong. sometimes your assumptions are just wrong. for instance you state that the radiation absorbed by CO2 is released so quickly that it doesnt matter but any slowing down of radiation from the speed of light is still slowing down. I dont really care why you think the way you do but I am concerned that other people are being misinformed by your obviously wrong explanations that you proclaim so loudly and confidently.