itfitzme
VIP Member
A simple replicable 200+ year old experiment proving what everybody but you knows. That you are simply wrong.
http://www2.ups.edu/faculty/jcevans/Pictet's experiment.pdf
Pictet's experiment? Interesting choice since it proves my case as well as any other. I can only suspect that you didn't understand his conclusions since you offer it up as evidence that I am wrong.
Pictet wasn't of the opinion that cold existed in and of itself but was instead an indication of negative heat, or the "privation" of heat. He believed that warm objects created a sort of tension in the air and the "heated air" around his thermometer would develop the same tension as the thermometer and would, by some mechanism reject any radiation from the thermometer.
In essence he described a standing wave between the air and the thermometer in which they essentially cancelled each other out...ie equilibrium.
He then took a flask of cold water or snow and placed it at the focal point of a concave mirror and a thermometer at the focal point of another mirror. As predicted by the Second Law of Thermodynamics, the temperature or the thermometer began to drop as it was radiating heat to the cooler flask. Interestingly, when the thermometer was placed somewhere close to, but not at the focal point of the mirror, the temperature appeared to remain unchanged...probably due to the limits of his thermometer. Prictet's experiment demonstrated one way energy flow from warm to cold.
That experiment brings to mind an experiment that you can perform in your own back yard for a minimal expense that will demonstrate undeniably that backradiation is not happening. If you like, I can IM to you a simple set of plans for a home made solar oven that I built myself for about 5 dollars. (I had some of the materials already in my workshop) If you have none of them, I doubt that you could spend more than 25 dollars.
Construct your solar oven. Be sure you have correctly identified the focal point. Then in the evening, point your solar oven at open sky. Place a thermometer at the focal point and you will see the temperature drop to well below ambient, precisely as the Second Law predicts. In fact, if the ambient temperature is 45 degrees F or less, you will see ice form in a bowl of water set at the focal point of your oven. If backradiation sufficient to warm the surface of the earth were actually happening, you would not see ice form when the temperature was 13 degrees above freezing.
You can point your oven at open sky during the daytime as well and again, you will see the temperature drop below the ambient temperature. Again, if backradiation were happening, then you would not see a temperature drop as your oven would be collecting and focusing the backradiation to a specific point which would cause the temperature to increase.
Pictet's experiment proves my point and achieved results that were predicted by the Second Law. The thermometer in the focal plane of a mirror reflecting a cold flask dropped in temperature...it did not remain in equlibrium with the room and it did not increase. The Second Law predicts that it would cool and that is exactly what it did. One way transfer of energy.
So tell me, which of the laws of physics do you believe predicts a greenhouse effect as it has been described by climate science.
He essen
What it proved of course was that the 32 degree F flask radiated heat that only had one way to warm the warmer themometer. Radiantly. It was an exact replica in that regard of GHGs radiantly warming the earth in spite of the fact that in most cases their absolute temperature is lower than earths.
Is that the last obstacle in the way of you understanding and accepting AGW?
Yeah, I'm not seeing it. Clearly, the body of science demonstrates that classical thermodynamic principles apply to macroscopic quantities, this was demonstrated by Einstein. And, classical thermo remains a solid science for macro systems. Statistical mechanics has since replaced it at a microscopic level.
While my performance in classical thermo was above par, for one semester, I make no claims to having retained a solid recollection of it's application beyond having spent many an hour thumbing through tables of enthalpy and entropy.
It is my understanding that, below the microscopic level, there remains the philosophical consideration that it still holds, to some degree. It seems, though, that there is no case for revoking it in the context of energy transition between microscopic particles.
At any moment in time, any molecule may emit a photon of such wavelength or energy that is consistent with the electron orbitals. The probability of doing so is dictated by quantum mechanics, not thermodynamics. And as spooky action at a distance applies to only particles that originated at the same place, at the same time, there is no mechanism that forbids a colder molecule from emiting a photon towards a warmer molecule. And as I am unaware of any principle that results in the photon carrying any information from whence it came, there seems no mechanism that will forbid the warmer molecule from absorbing that photon.
As such, it remains clear that a cold body does emit radiation towards a warmer body which does absorb it. All molecules, in a larger body, are not at identical energy levels. As such, the instantaneous temperature of that warmer body will increase. Never the less, as it does, it will then emit more radiation. Just as the instantaneous temperature of the colder body decreased and it will, however momentarily, emit less.
So, while, should such a refined measuring apperatus be possible, we would find that the warmer and colder bodies do not reach equilibrium in a direct and single directional manner, but rather, wiggle towards equilibrium, in a random walk that is analogous to the random walk of Brownian motion.
Still, I can think of no macroscopic device which would reveal this microscopic process as all macroscopic measurements are subject to thermal noise and it is, in fact, this random walk that accounts for the thermal noise itself.
Perhaps you are seeing something from the experiment that I am not, something that yields the logical conclusion that heat is being tramsfered, unmistakably, from the cold flask to the warmer thermometer. I am not seeing it.
Perhaps a page and paragraph. Viewing an 8-1/2 x 11" page, on a mobile, is frustrating my usual skill to absorb whole pages.
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